Today I separated the magnetic grains from the other material in dried sample of Sawmill's ground. The easiest way I found to do this was to hold a ferrite magnet with its end in the material. This would result in a big clump on that particular pole. Tapping the magnet would cause most of the the non-magnetic rock particles to fall off, so a couple of cycles of this did a pretty good separation. In fact I was surprised how little was non-magnetic. I reckon over 60% of the sample volume was magnetite particles.
A 10gm sample was weighed out as before and tested on the Bartington susceptibility meter. The low frequency susceptibility was 11,622 and the high frequency reading 11,551, which is nearly 5x that of the unseparated material. Also noted was the fact that for 10gm weight the sample pot was only half full. The specific gravity of magnetite is about 5 and many rocks are much less. the host rock here seems to be quite light, so this emphasises the fact that it will collect in pockets and gullies where there will be natural concentrations of the material. Not surprising therefore that it can cause difficulties for metal detectors.
I got a reading on 10 of the MVM, although this did not correlate with the frequency difference for some reason I have yet to investigate, but the last two digits in susceptibilities of this order are very variable. Shake the container and there could be a plus/minus difference of 20. The MVM consistently gave 10, which indicates a low level of viscosity signal for a PI unit.
For magnetite grains to become superparamagnetic, and give a viscous decay, they have to be smaller than 0.03um at room temperature, which is pretty darn small. This would likely explain the small value of the viscosity signal. Heating a sample should cause this to increase, which is another experiment worth doing.
I haven't found the figure I want yet for firing magnetite to get maghemite. The only thing found was that at 600degC maghemite and magnetite revert to hematite, which is only weakly magnetic. So it has to be less than that.
That temperature experiment in the previous but one paragraph wasn't worth doing, at least it would be better done a different way. For quickness I put the sample pot in the microwave. After only a few seconds it went off like a cannon. Now I have to clean magnetite off all the surfaces in the microwave and check out the dent in the top panel. Maybe its turned into maghemite.
Eric.