Yes, Fisher came out with an F-2/F-4 elliptical DD coil that plugs into the older Tekentics models including the Mark 1. I have one of these Fisher DD coils and they do work well. You'll loose some sensitivity but the DD cover is great, Haven't tried it with poor ground and not sure if it will help the Mark 1 in mineralized soil.
However, I heard Fisher changed the plug on later F-2/F-4 DD coils? So if your buddy is looking for a DD coil for his Mark 1 he'll need to get one of the first Fisher F-2/F-4 DD coils...Will enclose a pic below of my Modified Mark 1 with the Fisher DD coil.
Good luck,
Paul