Silver and copper are best at the lower frequency of 6.5khz while gold and nickle will be best at the higher frequency. We can think of this based on their conductivity. Copper and silver are better than gold and nickels. However, we are talking about great conductors even when we throw in iron. Higher frequency for lower conductive and lower frequency for higher conductive.
Iron has permeability, retention, and is magnetic, which causing it to look a lot like silver. So, we end up with iron responding great to a low frequency and out of step with nonmagnetic materials.
Higher Frequency - Gold and Nickle
Lower Frequency - Silver and Copper (Iron)
When we read about the signature of a metal this is what is being said. As examples, take a pieces of metal about the size of a flashlight, that are silver, iron, copper, and nickle and hit it with the same force like a tuning fork and it will have a specific ring. The general idea in we hit the target with a electromagnetic field. The different metals are in a sense going to ring depending on their signature frequency. The next step is to alloy the metals and see where they ring.
I would add to the coils for the X-terra 50 one at 3khz and then smaller coils for 6.5khz and the higher frequency. A nice small coil for the higher frequency should be a killer on small gold jewelry and really work through the trash. I have seen some very valuable small jewelry with nice diamonds that would make a great find.